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Image Search Results
Journal: Journal of inorganic biochemistry
Article Title: A divergent mode of activation of a nitrosyl iron complex with unusual antiangiogenic activity
doi: 10.1016/j.jinorgbio.2020.111133
Figure Lengend Snippet: Spectral changes investigated by stopped-flow measurement during the reaction of trans-[Fe(cyclam)(NO)Cl]2+ (5 mM) with GSH (150 mM) (A) and the same reaction between of trans-[Fe(cyclam)(NO)Cl]2+ (300 μM) with GSH (9 mM) by UV–Vis (B) in 0.5 M phosphate buffer pH 7.4 solution at 37 °C and under aerobic conditions. Inset: kinetic curve monitored at 541 nm (first order equation fit, in A kobs = 6.31 s−1, R2 = 0.9936, in B kobs = 6,93 × 10−5, R2 = 0.9830).
Article Snippet: Instruments, sample handling and preparations The absorption spectra in the UV–Vis range were obtained using the following spectrophotometers: Cary model 5000 UV/VIS–NIR (Varian/Agilent), Diode-Array Hewlett-Packard model 8453,
Techniques: